Glossary

Martensitic stainless steel is a category of stainless steel known for its high strength, hardness, and moderate corrosion resistance, achieved through heat treatment that transforms its crystal structure into martensite. It is characterized by a body-centered tetragonal (BCT) crystal structure, which forms when steel containing sufficient carbon is rapidly cooled or quenched from a high temperature. This gives martensitic stainless steels their distinctive ability to be hardened and tempered, much like carbon steels.

The composition of martensitic stainless steels typically includes 11.5% to 18% chromium and 0.1% to 1.2% carbon, with small amounts of other elements such as molybdenum, nickel, or vanadium to improve strength, corrosion resistance, and toughness. The chromium content provides the protective oxide layer that resists rust and oxidation, while the carbon allows for the formation of martensite during quenching, leading to significant hardness and wear resistance.

Unlike austenitic or ferritic stainless steels, martensitic grades are magnetic and can be heat treated to a wide range of hardness levels. However, this comes at a tradeoff: their corrosion resistance is generally lower, especially in environments involving chlorides or acids. They also tend to have reduced ductility and weldability compared to other stainless steel families.

Common martensitic grades include Type 410 (general-purpose, used for cutlery, valves, and turbine blades), Type 420 (high-carbon, used for surgical instruments and knives), and Type 440C (very high carbon, used for bearings, precision tools, and high-wear components). These steels are often used where mechanical strength, edge retention, and wear resistance are more critical than corrosion resistance.

In summary, martensitic stainless steels combine moderate corrosion resistance with exceptional hardness and strength, making them ideal for blades, tools, fasteners, shafts, and mechanical parts that require durability and resistance to wear. Their defining feature is that they can be hardened by heat treatment, which sets them apart from ferritic and austenitic stainless steels.