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Glossary

Vanadium Pentoxide (V₂O₅)

Vanadium Pentoxide (V₂O₅) is a bright yellow to rust-orange crystalline compound composed of vanadium and oxygen, and it is one of the most important industrial compounds of vanadium. Chemically, it serves as both an oxidizing agent and a catalyst, making it indispensable in metal production and chemical manufacturing.

In its solid form, vanadium pentoxide consists of layers of vanadium atoms surrounded by oxygen atoms in a distorted octahedral arrangement. It is amphoteric, meaning it can react with both acids and bases, and it exhibits multiple oxidation states, allowing it to easily gain or lose oxygen in chemical reactions. This redox flexibility is what makes V₂O₅ such a powerful catalyst.

The compound’s most important industrial use is as a catalyst in the Contact Process, which produces sulfuric acid—one of the world’s most heavily produced chemicals. In this process, V₂O₅ facilitates the conversion of sulfur dioxide (SO₂) to sulfur trioxide (SO₃) by transferring oxygen atoms efficiently. It’s also used in the manufacture of maleic anhydride, phthalic anhydride, and other organic intermediates.

In metallurgy, vanadium pentoxide is used to produce ferrovanadium alloys, which strengthen steel and improve resistance to heat and wear. When mixed with other metals, it imparts high tensile strength and fatigue resistance—qualities essential for aerospace components, tools, and high-performance steel.

V₂O₅ is also used in ceramics, glass, and pigments, where it acts as a colorant that gives yellow, green, or blue hues depending on oxidation conditions. In electronics and emerging energy technologies, it’s used in vanadium redox flow batteries and solid-state devices because of its ability to reversibly store and release oxygen ions.

However, vanadium pentoxide is toxic in dust or fume form. Inhalation or prolonged exposure can irritate the respiratory tract and cause health issues, so industrial handling requires proper ventilation and protective equipment.

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