Glossary

Precipitation hardening stainless steel, often abbreviated as PH stainless steel, is a class of stainless steel that achieves its exceptional high strength, hardness, and corrosion resistance through a specialized heat treatment process known as precipitation hardening (or age hardening). This process involves the controlled formation of very fine particles (precipitates) within the metal’s microstructure, which strengthen the material without significantly reducing its toughness or corrosion resistance.

Chemically, PH stainless steels contain chromium and nickel as their main alloying elements, similar to austenitic grades, but they also include copper, aluminum, titanium, or niobium to enable the precipitation-hardening effect. The chromium provides corrosion resistance, while the nickel stabilizes the austenitic or martensitic structure, and the additional elements form the fine precipitates that dramatically increase strength during heat treatment.

The hardening process occurs in three main stages: solution treatment, quenching, and aging. During solution treatment, the alloying elements are dissolved at high temperature. Quenching rapidly cools the material to lock these elements in a supersaturated solid solution. Finally, during aging, the metal is reheated to a moderate temperature, allowing controlled precipitation of intermetallic compounds that impede dislocation motion — the mechanism that gives the steel its high strength.

Depending on their metallurgical structure, PH stainless steels can be martensitic, semi-austenitic, or austenitic. The most common grade is 17-4 PH (UNS S17400), which contains roughly 17% chromium and 4% nickel, along with copper and niobium for hardening. It offers excellent strength, moderate corrosion resistance (similar to 304), and can be hardened to yield strengths exceeding 1,000 MPa (145 ksi). Other notable grades include 15-5 PH, 17-7 PH, and 13-8 Mo, each designed for specific combinations of toughness, hardness, and corrosion resistance.

Precipitation hardening stainless steels are used extensively in aerospace, nuclear, and petrochemical industries, as well as for valves, shafts, turbine components, fasteners, and high-performance mechanical parts that must maintain strength at both elevated and sub-zero temperatures.

In summary, precipitation hardening stainless steels combine the corrosion resistance of austenitic grades with the strength of martensitic steels, made possible through precise heat treatment. Their ability to achieve very high mechanical performance while maintaining corrosion resistance makes them ideal for critical applications where strength, durability, and reliability are equally important.